Методические вопросы применения метода ик-спектроскопии для определения кинетических параметров стадий на поверхности катализаторов

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  • Rea~.Kin~.C~al. Letr.,Vol. 18, No. 1-2,39-44(1981)

    ~ET0~I4qECKI/~ BOHPOC~ ~P~EHEHIi~ ~ET0~A [4K-C~EKTPOCK0~

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    HA HOBEPXHOCTM KATAZMSATOPOB

    A.A.Cono~eHH~o~ z A .A .~a~o~

    ~HC~y~ Kawaz~3a, Ho~oc~Szpc~, CCCP

    ~oc~yn~aa ~ pe~aK~ 17 Mapca 1981 Hp~H~a ~ ne~aT~ 22 Ma~ 1981

    Pa3odpaH~ ~eToAa~ec~e Bonpoc~, BOSHaSa#~ze npa on-

    pe~eneH~ E~HeT~qeOK~X napaMe~poB c~a~, ~poTe~a~x Ha HoBepxHOCT~ EaTS~MBSTOOOB, C HOMO~BD MeTO~a [/[K-OHeETDOO- EOHMM.

    Some methodological problems encountered in IR spectroscopic studies of the kinetic parameters of reaction steps on catalyst surfaces are discussed.

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    39

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    40

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    41

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    42

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    43

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    ~ITEPATYPA~

    i.J.Fahrenfort, L.L.Reijen, W.M.H.Sachtler: J.Electrochem., 6_s 216 (196o).

    2.A.Ueno, T.Onishi, K.Tamaru: Trans. Faraday Sot., 66,756 (1970~. 3.A.Ueno, T.Onishi, K~ Trans.Faraday Soc.,67,3585 (1971). 4.P.J.Kokes, A.L.Den~:Advan. Catal., 22, I (1972). 5.K.Tamaru, T.Onishi: Spectrosc. Left., ~, 133 (1975).

    6.B.~.CoKoaoBoKZ~, P.K.Bopec~oB, A.A.~aB~0B, A . r .AH~, D.M.~eKoq~XZH: ~AH CCCP 214, 1361 (1974).

    7.B.~.Co~os P.K.BopecI~oB, A .A .~a~oB, T.A.Fy~ps B.0.AHy@p~eHKo, 8.A.~OMa~s A.A.~yxHeBa, H.F.MaKOZMOB: ~AH CCCP, 216, 599 (1974).

    8.B.A.MaT~maK, A.A.KpHs A.A.Kas Ns~. AH CCCP, cop. xxM., 11, 2428 (1979).

    9.A.H.KapHayxo~: KZHeTZZa Z saTas 12, 1920 (1971). 10.~.A.~oxo~, S.~yc~, A.A.~aB~OB: Tes~c~ ~o~. BOeOO~SHO~

    ~o~. no Mexa~B~y EaT. pea~, ! , p.505, MOcEBa, 1978. 11.A.A.ConoMeHHZ~OB, ~.A.~oxoB, A.A.ZaB~OB: XSHOT~a n EaTa-

    44

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